List of Reagents

Full Review

Cl2 and Electrophilic Cl+ / radical Cl. reagents

  • Cl2 (with/without oxidant)
  • HCl/Cl - plus oxidant
  • N-Chlorosuccinimide (NCS)/Dichlorodimethylhydantoin (DCDMH)/ Trichloroisocyanuric acid (TCCA) Sodium dichloroisocyanurate NaDCC
  • NaOCl
  • SO2Cl2
  • CCl4/ C2Cl6

Reagents for deoxychlorination

  • HCl
  • (COCl)2
  • COCl2/ CCl3OCOOCCl3
  • Ph3P/Cl2 or CCl4
  • PhPOCl2
  • PCl3, PCl5, POCl3, SOCl2
  • TosCl/MesCl

Light Review

Nucleophilic sources of Cl-

  • KCl/NaCl/LiCl
  • nBu4NCl

Enzyme-catalyzed chlorination

Specific solvent issues with chlorination

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